The phosphorescence emission in undoped lead-halide Cs4PbBr6 single crystals at low temperature

Recently, all-inorganic cesium lead-halide perovskites have shown their promise for light emission applications, due to the excellent optical performance. Herein, we report that the initially nonphosphorescent undoped lead-halide Cs₄PbBr₆ single crystals (SCs) exhibit an ultralong phosphorescence emission under X-ray excitation at low temperatures. It is shown that the dramatic change has been taken place in radioluminescence spectra and the broad-band emission gradually appeared with the decrease of temperature. Below 210 K, the radioluminescence spectra can be deconvoluted into one narrow peak located at 530 nm and two broad peaks centered at 595 nm and 672 nm respectively. Subsequently, the time-dependent radioluminescence spectra in undoped lead-halide Cs₄PbBr₆ SCs were investigated. The ultralong phosphorescence emission can persist over 120 min at 70 K. We consider that ultralong phosphorescence originates from defect-related emission. To the best of our knowledge, our finding is the first time that undoped Cs₄PbBr₆ SCs exhibit the phosphorescence emission, which will offer a paradigm to motivate revolutionary applications on perovskite.     

Microstructure characterization of W-Ni-Fe heavy alloys with optimized metallographic preparation method

Tungsten heavy alloys (WHA) have been widely adopted in many engineering applications due to their excellent physicochemical properties. Microstructure characterization is a very powerful method ranging from testing materials properties to detecting material failures and defects. However, the microstructure of WHA was not well characterized with the sample prepared by conventional method of etching with strong acids, bases or oxidant after polishing for the coarse surface. To solve the problem, the exact characterization of W-Ni-Fe heavy alloys microstructure was conducted using the sample prepared by optimized polishing method. A series of experiments were conducted to find the suitable polishing conditions including polishing pad, abrasive slurry and slurry pH. The results show that a smooth and clear microstructure sample was obtained by polishing with alkaline colloidal silica and IC polishing pad, which contained few defects compared with that obtained by conventional method of etching after polishing. The microstructure of W-Ni-Fe heavy alloys was analyzed by XRD, EDS tests and EPMA detection. The slipping phenomenon was observed in nanoindentation test using the prepared sample for the first time and the mechanism of satisfactory microstructure sample preparation was illustrated.     

Numerical investigation of a direct ammonia tubular solid oxide fuel cell in comparison with hydrogen

Nowadays, carbon-rich fuels are the principal energy supply utilized for powering human society, and it will be continued for the next few decades. Connecting with this, modern energy technologies are very essential to convert the available limited carbon-rich fuels and other green alternative energies into useful energy efficiently with an insignificant environmental impression. Amongst all kinds of power generation systems, SOFCs running with high temperatures are emerging as a frontrunner in chemical to electrical transformation efficiency, allows the engagement of all-embracing fuel varieties with negligible environmental impact. This study investigates the effect of ammonia usage in tubular SOFC performance. Firstly, the use of ammonia and hydrogen in the electrolyte-supported SOFC (ES-SOFC) has investigated. Then, the effect of using ammonia in anode-supported SOFC (AS-SOFC), ES-SOFC and cathode-supported SOFC (CS–SOFC) on performance has been examined by using COMSOL software. As a result of the study performed, it is found that the ammonia can be used in tubular SOFC's as a carbon-free fuel and CS-SOFC shows better performance compared with ES-SOFC and AS-SOFC. Besides, the findings of this study indicate that the use of ammonia as a fuel for SOFCs is comparable to the use of hydrogen.     

Effect of pyrolysis temperature on the mechanical evolution of SiCf/SiC composites fabricated by PIP

Three types of SiC_f/SiC composites with a four-step three-dimensional SiC fibre preform and pyrocarbon interface fabricated via precursor infiltration and pyrolysis at 1100 °C, 1300 °C, and 1500 °C were heat-treated at 1300 °C under argon atmosphere for 50 h. The effects of the pyrolysis temperature on the microstructural and mechanical properties of the SiC_f/SiC composites were studied. With an increase in the pyrolysis temperature, the SiC crystallite size of the as-fabricated composites increased from 3.4 to 6.4 nm, and the flexural strength decreased from 742 ± 45 to 467 ± 38 MPa. After heat treatment, all the samples exhibited lower mechanical properties, accompanied by grain growth, mass loss, and the formation of open pores. The degree of mechanical degradation decreased with an increase in the pyrolysis temperature. The composites fabricated at 1500 °C exhibited the highest property retention rates with 90% flexural strength and 98% flexural modulus retained. The mechanism of the mechanical evolution after heat treatment was revealed, which suggested that the thermal stability of the mechanical properties is enhanced by the high crystallinity of the SiC matrix after pyrolysis at higher temperatures.     

Nonlinear robust dual-loop control for electro-hydraulic load simulator

This paper investigates on the high performance torque control of electro-hydraulic load simulator (EHLS). In order to suppress actuator׳s motion disturbance, a nonlinear robust dual-loop control scheme is developed, which consists of a open-loop nonlinear velocity feed-forward compensator and a closed-loop nonlinear deterministic robust torque controller. The main function of the open-loop compensator is to decouple actuator׳s active motion disturbance, whereas the torque loop controller aims at guaranteeing the dynamics performance of tracking torque reference. Besides actuator׳s motion disturbance, both the nonlinearity characteristics and friction problem of the EHLS system are taken into consideration in this paper. The effectiveness of the developed method are verified through comparative co-simulations and experiments.     

A semi-analytical approach for linear and non-linear analysis of unstiffened laminated composite cylinders and cones under axial,torsion and pressure loads

A semi-analytical model for the non-linear analysis of simply supported, unstiffened laminated composite cylinders and cones using the Ritz method and the Classical Laminated Plate Theory is proposed. A matrix notation is used to formulate the problem using Donnell׳s and Sanders׳ non-linear equations. The approximation functions proposed are capable to simulate the elephant׳s foot effect, a common phenomenon and a common failure mode for cylindrical and conical structures under axial compression. Axial, torsion and pressure loads can be applied individually or combined, and solutions for linear static, linear buckling and non-linear buckling analyses are presented and verified using a commercial finite element software. The presented non-linear buckling analyses used perturbation loads to create the initial geometric imperfections, showing the capability of the method for arbitrary imperfection patterns. The linear stiffness matrices are integrated analytically and for the conical structures an approximation is proposed to overcome the non-integrable expressions.     

Hierarchical multi-reservoir optimization modeling for real-world complexity with application to the Three Gorges system

High dimensionality in real-world multi-reservoir systems greatly hinders the application and popularity of evolutionary algorithms, especially for systems with heterogeneous units. An efficient hierarchical optimization framework is presented for search space reduction, determining the best water distributions, not only between cascade reservoirs, but also among different types of hydropower units. The framework is applied to the Three Gorges Project (TGP) system and the results demonstrate that the difficulties of multi-reservoir optimization caused by high dimensionality can be effectively solved by the proposed hierarchical method. For the day studied, power output could be increased by 6.79 GWh using an optimal decision with the same amount of water actually used; while the same amount of power could be generated with 2.59 × 10⁷ m³ less water compared to the historical policy. The methodology proposed is general in that it can be used for other reservoir systems and other types of heterogeneous unit generators.     

A derivative UKF for tightly coupled INS/GPS integrated navigation

The tightly coupled INS/GPS integration introduces nonlinearity to the measurement equation of the Kalman filter due to the use of raw GPS pseudorange measurements. The extended Kalman filter (EKF) is a typical method to address the nonlinearity by linearizing the pseudorange measurements. However, the linearization may cause large modeling error or even degraded navigation solution. To solve this problem, this paper constructs a nonlinear measurement equation by including the second-order term in the Taylor series of the pseudorange measurements. Nevertheless, when using the unscented Kalman filter (UKF) to the INS/GPS integration for navigation estimation, it causes a great amount of redundant computation in the prediction process due to the linear feature of system state equation, especially for the case with system state vector in much higher dimension than measurement vector. To overcome this drawback in computational burden, this paper further develops a derivative UKF based on the constructed nonlinear measurement equation. The derivative UKF adopts the concise form of the original Kalman filter (KF) to the prediction process and employs the unscented transformation technique to the update process. Theoretical analysis and simulation results demonstrate that the derivative UKF can achieve higher accuracy with a much smaller computational cost in comparison with the traditional UKF.     

The effect of hyperbranched polyester and zirconium slag nanoparticles on the impact resistance of epoxy resin thermosets

A hyperbranched polyester (HBP) was synthesized through a polymerization of AB₂ approach with succinic anhydride and diethanolamine. The effect of HBP and Zirconium slag nanoparticle (ZSN, a kind of solid waste in Zirconium industry) content on the toughness enhancement and morphology of diglycidyl ether of bisphenol A epoxy resin (DGEBA) thermosets was studied. The results indicated that HBP can greatly improve the impact strength (IS) of epoxy thermosets, but the flexural strength (FS) was decreased with increasing the HBP content. The IS of epoxy thermosets modified with ZSN was also improved, and the FS decreases as increase of ZSN. The thermosets modified with both HBP and ZSN showed excellent IS and FS. The toughening enhancement mechanism was also discussed.